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Category: chemistry – Page 7

Sunray-like ripples emerge on a frozen reaction front

Researchers in Belgium have unveiled a striking chemical reaction in which ripples along a frozen reaction front resemble the rays of a shining star. Publishing their results in Physical Review Letters, Anne De Wit and colleagues at the Université Libre de Bruxelles have shed new light on the patterns that emerge in reaction–diffusion systems, offering fresh insight into how similar structures arise in the natural world.

From forest fires to the spread of infectious diseases, many natural processes involve a “front” forming between two distinct states: be they burned and unburned forest, infected and healthy individuals, or any number of other examples in which one state spreads by consuming another.

Such behavior is often described using reaction–diffusion systems, where local reactions are coupled to transport processes such as diffusion. In the lab, this mechanism can be recreated by injecting a chemical compound into the center of a circular chamber filled with another reactant. If the chemistry is autocatalytic —where one of the reaction products catalyzes its own formation—a circular reaction front will form around the injection point.

Core–Shell Engineering of One-Dimensional Cadmium Sulfide for Solar Energy Conversion

Fabricating efficient photocatalysts that can be used in solar-to-fuel conversion and to enhance the photochemical reaction rate is essential to the current energy crisis and climate changes due to the excessive usage of nonrenewable fossil fuels.

Frontiers: Biological membranes are complex, heterogeneous, and dynamic systems that play roles in the compartmentalization and protection of cells from the environment

It is still a challenge to elucidate kinetics and real-time transport routes for molecules through biological membranes in live cells. Currently, by developing and employing super-resolution microscopy; increasing evidence indicates channels and transporter nano-organization and dynamics within membranes play an important role in these regulatory mechanisms. Here we review recent advances and discuss the major advantages and disadvantages of using super-resolution microscopy to investigate protein organization and transport within plasma membranes.

The mammalian plasma membrane (PM) is a complex assembly of lipids and proteins that separates the cell’s interior from the outside environment (Ingolfsson et al., 2014). The multiple collective processes that take place within membranes have a strong impact not only on the cellular behavior but also on its biochemistry. Understanding these processes poses a challenge due to the often complex and multiple interactions among membrane components (Stone et al., 2017). Moreover, the PM surface accommodates different types of lipid and protein clusters (Saka et al., 2014; Owen et al., 2012; Sezgin, 2017), even though the functional role of the clustering on the membrane surface has not yet been fully understood.

First-principles approaches and concepts to simulate electrochemical interfaces

State-of-the-art approaches for modelling electrified solid–electrolyte interfaces are critically discussed, highlighting key challenges in incorporating thermodynamic open-boundary conditions, large electrostatic potentials and their dynamic fluctuations into realistic ab initio simulations.

GOOD LUCK, HAVE FUN, DON’T DIE — Welcome To The Perfect Prison

Gore Verbinski’s Good Luck, Have Fun, Dont Die hits like a nasty mirror held up at the worst possible angle. On paper, the setup sounds almost playful: a “Man From the Future” drops into a diner in Los Angeles and has to recruit the exact combination of disgruntled strangers for a one-night mission to stop a rogue AI. But the horror isn’t metal skeletons and laser fire. It’s the idea that the end of humanity doesn’t arrive with an explosion. It arrives with an upgrade. A perfectly tuned stream of algorithmic entertainment that doesn’t merely distract people—it replaces them. A manufactured paradise so frictionless, so gratifying, so chemically rewarding, that the messy, strenuous, inconvenient act of being human starts to feel obsolete.

#goodluckhavefundontdie #samrockwell #ai #algorithm.

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Stick chemistry: High-throughput method for finding new molecular glues

Molecular glues are enjoying the spotlight, but discovering new ones is often a matter of luck. A new method, developed by Scripps Research chemist Michael Erb and colleagues, aims to discover new glues more intentionally with a “target-based” approach.

Click chemistry method opens up avenues for intentional glue discovery by .

Chemistry-powered ‘breathing’ membrane opens and closes tiny pores on its own

Ion channels are narrow passageways that play a pivotal role in many biological processes. To model how ions move through these tight spaces, pores need to be fabricated at very small length scales. The narrowest regions of ion channels can be just a few angstroms wide, about the size of individual atoms, making reproducible and precise fabrication a major challenge in modern nanotechnology.

In a study published in Nature Communications, researchers at The University of Osaka have addressed this challenge by using a miniature electrochemical reactor to create ultra-small pores approaching subnanometer dimensions.

In biological cells, ions flow in and out through channels in cell membranes. This ion flow is the basis for generating electrical signals, such as nerve impulses that trigger muscle contraction. The channels themselves are made of proteins and can have angstrom-wide narrow regions. Conformational changes of these proteins in response to external stimuli open and close the channels.

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