Researchers from the Molecular Physics and Physical Chemistry departments of the Fritz Haber Institute have shown how two highly synchronized infrared (IR) laser beams can control molecules as they switch between different structural conformations. Their study provides a new window into how molecules rearrange themselves during chemical reactions, offering fundamental insights into the microscopic processes that govern chemistry.

Chemical reactions are the foundation of all the processes that sustain life. Researchers around the world are working to develop precise physical descriptions of these processes to better understand, predict or specifically control them.

In chemical reactions, molecules undergo various structural transformations, changing their 3D shapes between different conformations. These changes can be visualized as movements across an energy landscape, where the shape of the terrain determines how fast a reaction proceeds. Similar to a ball rolling through a hilly landscape, a molecule must overcome energy barriers—the “mountains”—to settle into a new, stable state in the next “valley.”

Scientists at the U.S. Department of Energy’s (DOE) Brookhaven National Laboratory and their collaborators have demonstrated a promising new approach for converting methane—the primary component of natural gas—into liquid chemicals that are precursors for many industrial chemicals and fuels. The research, described in a paper just published in Advanced Functional Materials, shows how molybdenum disulfide (MoS₂), an earth-abundant industrial catalyst, can be used with minimal tweaking to selectively convert methane into methyl peroxide and other liquid oxygenate compounds at temperatures below 100°C (212°F). Methyl peroxide is a precursor for making methanol, an energy-dense liquid fuel that can be transported easily.

“The fact that this catalyst is an earth-abundant, domestically sourced material could change the game for converting natural gas into liquid chemicals,” said Brookhaven Lab chemist Sanjaya Senanayake, a corresponding author on the publication. “The catalyst achieves very high yields and high specificity for making important precursors for methanol and a wide range of other industrial processes.”

The project is part of a long-term strategy of the Catalysis: Reactivity and Structure group in Brookhaven Lab’s Chemistry Division to develop methane-conversion catalysts and processes. This group includes co-authors Senanayake, chemist Juan Jiménez and research associate Arephin Islam—all co-authors on the new publication.