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May 11, 2023

Researchers discover liquid quasicrystal with dodecagonal tiling pattern

Posted by in categories: chemistry, materials

An unusual quasicrystal has been discovered by a team from the Martin Luther University Halle-Wittenberg (MLU), the University of Sheffield and Xi’an Jiaotong University. It has a dodecagonal honeycomb structure that has never been seen before. Until now, similar quasicrystals were only known to come in a solid—not liquid—form. The team presents its results in the journal Nature Chemistry.

Quasicrystals have a special structure. They have a regular pattern similar to normal crystals, however, in normal crystals, the arrangement of the individual components is repeated over and over at . In the case of quasicrystals, the components do not fit together in such a periodic pattern. This special structure gives them special properties that normal crystals do not have.

The newly discovered consists of dodecagons, which in turn are made up of a mixture of triangular, square and, for the first time, trapezoidal shaped cells. These are generated from the self-assembly of “T-shaped” molecules. “We have discovered a perfectly ordered liquid quasicrystal. Such a material has never been seen before,” says chemist Professor Carsten Tschierske at MLU.

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