Lifeboat Foundation

Despite the young age of the research field, substantial progress has been made in the study of metal halide perovskite nanocrystals (HPNCs). Just as their thin-film counterparts are used for light absorption in solar cells, they are on the way to revolutionizing research on novel chromophores for light emission applications. Exciting physics arising from their peculiar structural, electronic, and excitonic properties are being discovered with breathtaking speed. Many things we have learned from the study of conventional semiconductor quantum dots (CSQDs) of II–VI (e.g., CdSe), IV–VI (e.g., PbS), and III–V (e.g., InP) compounds have to be thought over, as HPNCs behave differently. This Feature Article compares both families of nanocrystals and then focuses on approaches for substituting toxic heavy metals without sacrificing the unique optical properties as well as on surface coating strategies for enhancing the long-term stability.

• • Top of Page
  • Abstract
  • Introduction
  • Optical Properties of CSQDs and HPNCs
  • Specificities of Cd- and Pb-Containing NCs Favoring Outstanding Optoelectronic Properties
  • General Strategies for Replacing Toxic Heavy Metals in Nanocrystals
  • Conclusions and Perspectives
  • References

In the early 1980s the quest for novel photocatalysts, fueled by the oil crisis in the preceding decade, led to the discovery of semiconductor quantum dots. Pioneering works by Efros, Brus, and Henglein showed both experimentally and theoretically that the reduction of size of semiconductor particles (e.g., CdS) down to the nanometer range induces a significant change in their band gap energy.(1−3) The underlying quantum confinement effect, occurring when the nanocrystal size is (significantly) smaller than twice the exciton Bohr radius of the semiconductor material (Table 1), leads to an increase, scaling with 1/r, of the band gap energy. It also gives rise to the appearance of discrete energy levels at the place of continuous valence and conduction energy bands. In the same period Ekimov as well as Itoh and co-workers observed quantum confinement in small CuCl crystallites embedded in a glass or a NaCl matrix.

By ricocheting neutrons off the atoms of yttrium manganite (YMnO₃) heated to 3,000 degrees Fahrenheit, researchers have discovered the atomic mechanisms that give the unusual material its rare electromagnetic properties. The discovery could help scientists develop new materials with similar properties for novel computing devices and micro-actuators.

The experiment was conducted as a collaboration between Duke University and Oak Ridge National Laboratory (ORNL) and appeared online in Nature Communications on January 2, 2018.

Ferromagnetism is the scientific term for the phenomenon responsible for permanent magnets like iron. Such materials exist because their molecular structure consists of tiny magnetic patches that all point in the same direction. Each patch, or domain, is said to have a magnetic dipole moment, with a north and a south pole, which, added together, produce the magnetic fields so often seen at work on refrigerator doors.

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Electronics rely on the movement of negatively-charged electrons. Physicists strive to understand the forces that push these particles into motion, with the goal of harnessing their power in new technologies. Quantum computers, for instance, employ a fleet of precisely controlled electrons to take on goliath computational tasks. Recently, researchers at the Okinawa Institute of Science and Technology Graduate University (OIST) demonstrated how microwaves cut in on the movements of electrons. The findings may contribute to future quantum computing technology.

The logic operations of normal computers are based on zeros and ones, and this binary code limits the volume and type of information the machines can process. Subatomic particles can exist in more than two discrete states, so quantum computers harness electrons to crunch complex data and perform functions at whiplash speed. To keep electrons in limbo for experiments, scientists capture the particles and expose them to forces that alter their behavior.

In the new study, published December 18, 2018 in Physical Review B, OIST researchers trapped electrons in a frigid, vacuum-sealed chamber and subjected them to microwaves. The particles and light altered each other’s movement and exchanged energy, which suggests the sealed system could potentially be used to store quantum information – a microchip of the future.

The history of the universe is predicated on the idea that, compared to today, the universe was hotter and more symmetric in its early phase. Scientists have thought this because of the Higgs Boson finding—the particle that gives mass to all other fundamental particles. The concept is that as one analyzes time back toward the Big Bang, the universe gets hotter and the Higgs phase changes to one where everything became massless. Now, physicists are presenting a new theory that suggests an alternative history of the universe is possible.

Possible quantum computing at room temperature. Scientists working with hexagonal boron nitride, which allows them to work in two-dimensional arrays. Simpler than using 3D objects such as diamonds.

Researchers have now demonstrated a new hardware platform based on isolated electron spins in a two-dimensional material. The electrons are trapped by defects in sheets of hexagonal boron nitride, a one-atom-thick semiconductor material, and the researchers were able to optically detect the system’s quantum states.

Particle physics needs a larger particle accelerator. Perhaps even one using black holes.

Quantum physics sets the laws that dominate the universe at a small scale. The ability to harness quantum phenomena could lead to machines like quantum computers, which are predicted to perform certain calculations much faster than conventional computers. One major problem with building quantum processors is that the tracking and controlling quantum systems in real time is a difficult task because quantum systems are overwhelmingly fragile: Manipulating these systems carelessly introduces significant errors in the final result. New work by a team at Aalto could lead to precise quantum computers.

The researchers report controlling quantum phenomena in a custom-designed electrical circuit called a transmon. Chilling a transmon chip to within a few thousandths of a degree above absolute zero induces a quantum state, and the chip starts to behave like an artificial atom. One of the quantum features that interests researchers is that the energy of the transmon can only take specific values, called energy levels. The energy levels are like steps on a ladder: A person climbing the ladder must occupy a step, and can’t hover somewhere between two steps. Likewise, the transmon energy can only occupy the set values of the energy levels. Shining microwaves on the circuit induces the transmon to absorb the energy and climb up the rungs of the ladder.

In work published 8 February in the journal Science Advances, the group from Aalto University led by Docent Sorin Paraoanu, senior university lecturer in the Department of Applied Physics, has made the transmon jump more than one energy level in a single go. Previously, this has been possible only by very gentle and slow adjustments of the microwave signals that control the device. In the new work, an additional microwave control signal shaped in a very specific way allows a fast, precise change of the energy level. Dr. Antti Vepsäläinen, the lead author, says, “We have a saying in Finland: ‘hiljaa hyvää tulee’ (slowly does it). But we managed to show that by continuously correcting the state of the system, we can drive this process more rapidly and at high fidelity.”

The quantum internet will require fast-moving data and the Australian National University believes it has found a way to measure information stored in light particles which will pave the way for a safe “data superhighway”.

Circa 2018

Researchers have demonstrated nanomaterial-based white-light-emitting diodes (LEDs) that exhibit a record luminous efficiency of 105 lumens per watt. Luminous efficiency is a measure of how well a light source uses power to generate light. With further development, the new LEDs could reach efficiencies over 200 lumens per watt, making them a promising energy-efficient lighting source for homes, offices and televisions.

“Efficient LEDs have strong potential for saving energy and protecting the environment,” said research leader Sedat Nizamoglu, Koç University, Turkey. “Replacing conventional lighting sources with LEDs with an efficiency of 200 lumens per watt would decrease the global electricity consumed for lighting by more than half. That reduction is equal to the electricity created by 230 typical 500-megawatt coal plants and would reduce greenhouse gas emissions by 200 million tons.”

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